Alternating strings and clusters in suspensions of charged colloids
J. C. Everts, M. N. van der Linden, A. van Blaaderen and R. van Roij
Soft Matter, 2016, 12, 6610-6620
We report the formation of alternating strings and clusters in a binary suspension of repulsive charged colloids with double layers larger than the particle size. Within a binary cell model we include many-body and charge-regulation effects under the assumption of a constant surface potential, and consider their repercussions on the two-particle interaction potential. We find that the formation of induced dipoles close to a charge-reversed state may explain the formation of these structures. Finally, we will touch upon the formation of dumbbells and small clusters in a one-component system, where the effective electrostatic interaction is always repulsive.